[임병권교수님_Nano letters] Direct Chemical Synthesis of Plasmonic Black Colloidal Gold Superparticles wit > Research Highlight

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[임병권교수님_Nano letters] Direct Chemical Synthesis of Plasmonic Black Col…

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댓글 1건 조회 385회 작성일 21-04-19 13:34

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□ 논문제목: Direct Chemical Synthesis of Plasmonic Black Colloidal Gold Superparticles with Broadband Absorption Properties
□ 게재 학술지명: Nano letters
□ 주저자: 임 병 권
□ IF : 12.08
□ 논문소개
 

광대역  흡수체는  물질 상호 작용에 대한 이해와 표면 강화 분광기태양 에너지 변환광열 요법  새로운 광전자 장치의 제조를 비롯한 많은 응용 분야에서도 매우 중요하다이러한 광대역 빛 흡수 특성은 플라즈몬 금속 나노입자들의 자기 조립을 통해 유도 할 수 있다그 예로 금 나노입자들이 자기조립되어 형성된 초입자, hollow colloidosome 같은 경우 가시광 및 근적외선 영역에서 광대역 흡수를 보인다그러나 이러한 콜로이드 초입자 제조에 있어 나노입자 합성 후 이어지는 조립 공정을 필요로 하며이는 용매 또는 리간드 교환을 포함하는 다수의 단계를 필요로 하여 힘들고 시간 소모적이다. 

본 논문은 금 전구체와 이원 용매를 사용하여 자기조립된 콜로이드  초입자를 합성하는 간단한 단일 단계 방법을 보고합니다본 방법은 형성된  나노입자와 용매 사이의 solvophobic interaction에 의한 나노입자의 자기조립을 기반으로 한다 현상을 이용함으로써나노입자 자기조립을 유도하는 추가 공정을 필요로 하지 않고 매우 짧은 시간 내에 콜로이드  초입자를 생산할  있다합성된  초입자는 가시광  영역에 걸쳐 강한 흡수를 보이며  때문에 검은 색을 띈다또한용액 공정을 이용한 박막 제조가 가능하며제조된 초입자 박막은 400 nm 에서 2.5 μ 광범위한 파장에서 매우 낮은 투과율  반사되는  없이 거의 완벽한 흡수율 (> 97.5 %)  나타냈다이러한  초입자의 광대역 흡수 특성을 이용하여 광대역 surface-enhanced Raman spectroscopy (SERS) 기판 재료로의 가능성  효율적인 photothermal 특성을 확인하였다.

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